Ein neues Selten-Erd-Metall(III)-Oxidchlorid-Oxotellurat(IV): Nd5O4Cl3[TeO3]2 A New Rare Earth-Metal(III) Oxide Chloride Oxotellurate(IV): Nd5O4Cl3[TeO3]2
نویسندگان
چکیده
Pale violet, plate-like single crystals of the title compound, neodymium(III) oxide chloride oxotellurate(IV) Nd5O4Cl3[TeO3]2, can be obtained by the reaction of Nd2O3 with NdCl3 and TeO2 in equimolar ratios in evacuated silica ampoules within five days at 775 ◦Cwith an excess of CsCl added as fluxing agent. Nd5O4Cl3[TeO3]2 crystallizes in the monoclinic space group C2/m (no. 12) with the lattice parameters a = 1270.61(9), b = 562.70(4), c = 1008.97(8) pm, β = 90.784(3)◦ and Z = 2, and is thus isostructural to the lanthanoid(III) oxide halide oxoselenates(IV) Tb5O4Cl3[SeO3]2 and Gd5O4Br3[SeO3]2. The crystal structure exhibits three crystallographically different Nd3+ cations, of which (Nd1)3+ has a purely oxidic coordination sphere of eight oxide anions building up a square prism. (Nd2)3+ and (Nd3)3+ are both coordinated by oxide and chloride anions. The coordination polyhedron around (Nd2)3+ is a trigonal prism of oxide anions that is capped by one chloride anion to give a coordination number of seven. (Nd3)3+ resides in an eightfold coordination of five oxide and three chloride anions forming a square antiprism. All (O1)2− anions are surrounded tetrahedrally by Nd3+ cations as [ONd4] units. These tetrahedra share common edges and vertices to generate two-dimensional infinite layers of the composition ∞{[O4Nd5]}, which extend parallel to the (001) plane. The chloride anions (Cl1)− are connecting those slabs via Nd3–Cl1–Nd3 bridges along the [001] direction, while the (Cl2)− anions alternate with the Te4+ cations above and below the layers. The three-dimensional crystal structure of Nd5O4Cl3[TeO3]2 is completed by Te4+ cations, which are bonded to one (O2)2− and two (O3)2− anions to form ψ1-tetrahedra [TeO3]2− with a nonbinding, stereochemically active electron pair (“lone pair”) pointing into the free space between the chloride-decorated ∞{[O4Nd5]} layers.
منابع مشابه
Crystal structure of dilead(II) oxochromate(VI) oxotellurate(IV)
Reaction of chromium(III) precursors with TeO2 in PbF2/PbO melts in air led to oxidation of chromium(III) to chromium(VI), whereas tellurium remained its oxidation state of IV. In the resulting title compound, Pb2(CrO4)(TeO3), the two types of anions are isolated from each other, hence a double salt is formed. The two independent Pb2+ cations exhibit coordination number nine under formation of ...
متن کاملYCu(TeO3)2(NO3)(H2O)3: a novel layered tellurite
A new hydrated yttrium copper tellurite nitrate, yttrium(III) copper(II) bis-[trioxidotellurate(IV)] nitrate trihydrate, has been synthesized hydro-thermally in a Teflon-lined autoclave and structurally determined using synchrotron radiation. The new phase is the first example containing yttrium, copper and tellurium in one structure. Its crystal structure is unique, with relatively strongly bo...
متن کاملDetermination of the Correct Composition of “Hydrous Lead(II) Oxotellurate(IV)” as PbTeO3, Crystallizing as a New Polymorph
In previous studies, it has been reported that the crystalline product precipitated from the reaction of aqueous solutions of lead(II) salts with sodium oxotellurate(IV) is hydrous lead(II) oxotellurate(IV); however, there have been conflicting specifications of the water content, and the crystal structure of the product is yet undetermined. During the present study, it was shown that the preci...
متن کاملNaFe(TeO3)2
The hydro-thermally prepared title compound, sodium iron(III) bis-[trioxotellurate(IV)], is isotypic with its Ga(III) analogue and consists of corrugated layers with an overall composition of [FeTe(2)O(6)](-) together with Na(+) cations. The layers extend parallel to (001) and are made up of [Fe(2)O(10)] edge-shared octa-hedral dimers and TeO(3) trigonal pyramids sharing vertices. The Na(+) cat...
متن کاملCrystal structure of ammonium divanadium(IV,V) tellurium(IV) heptaoxide
The polyhedral building blocks of the layered inorganic network in the mixed-valence title compound, (NH4)(V(IV)O2)(V(V)O2)(TeO3), are vertex-sharing V(V)O4 tetra-hedra, distorted V(IV)O6 octa-hedra and TeO3 pyramids, which are linked by V-O-V and V-O-Te bonds, forming double layers lying parallel to (100). The presumed Te(IV) lone-pairs of electrons appear to be directed inwards into cavities ...
متن کامل